The conversion of but − 1 − ene into 2 − methoxybutane . Interpretation: The conversion of the given reactions is to be stated. Concept introduction: Oxymercuration-demercuration is one of the methods used to convert alkenes into alcohols. This type of reaction follows Markovinokov’s rule. According to Markovnikov’s rule, the positive part of acid gets attached to that carbon atom in C=C bond which carries maximum number of hydrogen atoms and the negative part of acid gets attached to that carbon atom in C=C bond which has minimum number of hydrogen atoms.

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Answer 1

Question

Chapter 8.6, Problem 8.9P

(a)

Interpretation Introduction

To determine: The conversion of but−1−ene into 2−methoxybutane.

Interpretation: The conversion of the given reactions is to be stated.

Concept introduction: Oxymercuration-demercuration is one of the methods used to convert alkenes into alcohols. This type of reaction follows Markovinokov’s rule.

According to Markovnikov’s rule, the positive part of acid gets attached to that carbon atom in C=C bond which carries maximum number of hydrogen atoms and the negative part of acid gets attached to that carbon atom in C=C bond which has minimum number of hydrogen atoms.

(b)

Interpretation Introduction

To determine: The conversion of 1−iodo−2−methylcyclopentane into 1−methylcyclopentanol.

Interpretation: The conversion of the given reactions is to be stated.

Concept introduction: The general steps followed by Oxymercuration-demercuration reaction are stated below:

Formation of mercurinium ion.

Attack of water on mercurinium ion to give alcohol.

Demercuration

(c)

Interpretation Introduction

To determine: The conversion of 3−methylpent−1−ene into 3−methylpentan−2−ol.

Interpretation: The conversion of the given reactions is to be stated.

Concept introduction: Oxymercuration-demercuration is one of the methods used to convert alkenes into alcohols. This type of reaction follows Markovinokov’s rule.

According to Markovnikov’s rule, the positive part of acid gets attached to that carbon atom in C=C bond which carries maximum number of hydrogen atoms and the negative part of acid will attach to that carbon atom in C=C bond which has minimum number of hydrogen atoms.

The general steps followed by Oxymercuration-demercuration reaction are stated below:

Formation of mercurinium ion.

Attack of water on mercurinium ion to give alcohol.

Demercuration

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2. Name each alkyne. a. CH3CH₂CH₂C=CH b. CH3CH₂CH₂C=CCH3 3. Predict the product of the following reactions. a. CH = CCH3 + HCI b. CH CCH₂CH3 + O2

Draw the products obtained from the SN2 reaction of a. 2-bromobutane and methoxide ion. b. (R)-2-bromobutane and methoxide ion. c. (S)-3-chlorohexane and hydroxide ion. d. 3-iodopentane and hydroxide ion.

Draw the organic products formed when cyclopentene is treated with each reagent. With some reagents, no reaction occurs. a.H2 + Pd-C b.H2 + Lindlar catalyst c.Na, NH3 d.CH3CO3H e.[1] CH3CO3H; [2] H2O, HO− f.[1]OsO4 + NMO; [2] NaHSO3, H2O g.KMnO4, H2O, HO− h.[1] LiAlH4; [2] H2O i. [1] O3; [2] CH3SCH3 j.(CH3)3COOH, Ti[OCH(CH3)2]4, (−)-DET k.mCPBA l.Product in (k); then [1] LiAlH4; [2] H2O

Answer 2

Question

Chapter 8.6, Problem 8.9P

(a)

Interpretation Introduction

To determine: The conversion of but−1−ene into 2−methoxybutane.

Interpretation: The conversion of the given reactions is to be stated.

Concept introduction: Oxymercuration-demercuration is one of the methods used to convert alkenes into alcohols. This type of reaction follows Markovinokov’s rule.

According to Markovnikov’s rule, the positive part of acid gets attached to that carbon atom in C=C bond which carries maximum number of hydrogen atoms and the negative part of acid gets attached to that carbon atom in C=C bond which has minimum number of hydrogen atoms.

(b)

Interpretation Introduction

To determine: The conversion of 1−iodo−2−methylcyclopentane into 1−methylcyclopentanol.

Interpretation: The conversion of the given reactions is to be stated.

Concept introduction: The general steps followed by Oxymercuration-demercuration reaction are stated below:

Formation of mercurinium ion.

Attack of water on mercurinium ion to give alcohol.

Demercuration

(c)

Interpretation Introduction

To determine: The conversion of 3−methylpent−1−ene into 3−methylpentan−2−ol.

Interpretation: The conversion of the given reactions is to be stated.

Concept introduction: Oxymercuration-demercuration is one of the methods used to convert alkenes into alcohols. This type of reaction follows Markovinokov’s rule.

According to Markovnikov’s rule, the positive part of acid gets attached to that carbon atom in C=C bond which carries maximum number of hydrogen atoms and the negative part of acid will attach to that carbon atom in C=C bond which has minimum number of hydrogen atoms.

The general steps followed by Oxymercuration-demercuration reaction are stated below:

Formation of mercurinium ion.

Attack of water on mercurinium ion to give alcohol.

Demercuration

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Answer 3

Question

Chapter 8.6, Problem 8.9P

(a)

Interpretation Introduction

To determine: The conversion of but−1−ene into 2−methoxybutane.

Interpretation: The conversion of the given reactions is to be stated.

Concept introduction: Oxymercuration-demercuration is one of the methods used to convert alkenes into alcohols. This type of reaction follows Markovinokov’s rule.

According to Markovnikov’s rule, the positive part of acid gets attached to that carbon atom in C=C bond which carries maximum number of hydrogen atoms and the negative part of acid gets attached to that carbon atom in C=C bond which has minimum number of hydrogen atoms.

(b)

Interpretation Introduction

To determine: The conversion of 1−iodo−2−methylcyclopentane into 1−methylcyclopentanol.

Interpretation: The conversion of the given reactions is to be stated.

Concept introduction: The general steps followed by Oxymercuration-demercuration reaction are stated below:

Formation of mercurinium ion.

Attack of water on mercurinium ion to give alcohol.

Demercuration

(c)

Interpretation Introduction

To determine: The conversion of 3−methylpent−1−ene into 3−methylpentan−2−ol.

Interpretation: The conversion of the given reactions is to be stated.

Concept introduction: Oxymercuration-demercuration is one of the methods used to convert alkenes into alcohols. This type of reaction follows Markovinokov’s rule.

According to Markovnikov’s rule, the positive part of acid gets attached to that carbon atom in C=C bond which carries maximum number of hydrogen atoms and the negative part of acid will attach to that carbon atom in C=C bond which has minimum number of hydrogen atoms.

The general steps followed by Oxymercuration-demercuration reaction are stated below:

Formation of mercurinium ion.

Attack of water on mercurinium ion to give alcohol.

Demercuration

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Answer 4

Question

Chapter 8.6, Problem 8.9P

(a)

Interpretation Introduction

To determine: The conversion of but−1−ene into 2−methoxybutane.

Interpretation: The conversion of the given reactions is to be stated.

Concept introduction: Oxymercuration-demercuration is one of the methods used to convert alkenes into alcohols. This type of reaction follows Markovinokov’s rule.

According to Markovnikov’s rule, the positive part of acid gets attached to that carbon atom in C=C bond which carries maximum number of hydrogen atoms and the negative part of acid gets attached to that carbon atom in C=C bond which has minimum number of hydrogen atoms.

(b)

Interpretation Introduction

To determine: The conversion of 1−iodo−2−methylcyclopentane into 1−methylcyclopentanol.

Interpretation: The conversion of the given reactions is to be stated.

Concept introduction: The general steps followed by Oxymercuration-demercuration reaction are stated below:

Formation of mercurinium ion.

Attack of water on mercurinium ion to give alcohol.

Demercuration

(c)

Interpretation Introduction

To determine: The conversion of 3−methylpent−1−ene into 3−methylpentan−2−ol.

Interpretation: The conversion of the given reactions is to be stated.

Concept introduction: Oxymercuration-demercuration is one of the methods used to convert alkenes into alcohols. This type of reaction follows Markovinokov’s rule.

According to Markovnikov’s rule, the positive part of acid gets attached to that carbon atom in C=C bond which carries maximum number of hydrogen atoms and the negative part of acid will attach to that carbon atom in C=C bond which has minimum number of hydrogen atoms.

The general steps followed by Oxymercuration-demercuration reaction are stated below:

Formation of mercurinium ion.

Attack of water on mercurinium ion to give alcohol.

Demercuration

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Answer 5

Chapter 8.6, Problem 8.9P

(a)

Interpretation Introduction

To determine: The conversion of but−1−ene into 2−methoxybutane.

Interpretation: The conversion of the given reactions is to be stated.

Concept introduction: Oxymercuration-demercuration is one of the methods used to convert alkenes into alcohols. This type of reaction follows Markovinokov’s rule.

According to Markovnikov’s rule, the positive part of acid gets attached to that carbon atom in C=C bond which carries maximum number of hydrogen atoms and the negative part of acid gets attached to that carbon atom in C=C bond which has minimum number of hydrogen atoms.

(b)

Interpretation Introduction

To determine: The conversion of 1−iodo−2−methylcyclopentane into 1−methylcyclopentanol.

Interpretation: The conversion of the given reactions is to be stated.

Concept introduction: The general steps followed by Oxymercuration-demercuration reaction are stated below:

Formation of mercurinium ion.

Attack of water on mercurinium ion to give alcohol.

Demercuration

(c)

Interpretation Introduction

To determine: The conversion of 3−methylpent−1−ene into 3−methylpentan−2−ol.

Interpretation: The conversion of the given reactions is to be stated.

Concept introduction: Oxymercuration-demercuration is one of the methods used to convert alkenes into alcohols. This type of reaction follows Markovinokov’s rule.

According to Markovnikov’s rule, the positive part of acid gets attached to that carbon atom in C=C bond which carries maximum number of hydrogen atoms and the negative part of acid will attach to that carbon atom in C=C bond which has minimum number of hydrogen atoms.

The general steps followed by Oxymercuration-demercuration reaction are stated below:

Formation of mercurinium ion.

Attack of water on mercurinium ion to give alcohol.

Demercuration

Answer 6

Chapter 8.6, Problem 8.9P

(a)

Interpretation Introduction

To determine: The conversion of but−1−ene into 2−methoxybutane.

Interpretation: The conversion of the given reactions is to be stated.

Concept introduction: Oxymercuration-demercuration is one of the methods used to convert alkenes into alcohols. This type of reaction follows Markovinokov’s rule.

According to Markovnikov’s rule, the positive part of acid gets attached to that carbon atom in C=C bond which carries maximum number of hydrogen atoms and the negative part of acid gets attached to that carbon atom in C=C bond which has minimum number of hydrogen atoms.

Answer 7

Chapter 8.6, Problem 8.9P

(a)

Interpretation Introduction

To determine: The conversion of but−1−ene into 2−methoxybutane.

Interpretation: The conversion of the given reactions is to be stated.

Concept introduction: Oxymercuration-demercuration is one of the methods used to convert alkenes into alcohols. This type of reaction follows Markovinokov’s rule.

According to Markovnikov’s rule, the positive part of acid gets attached to that carbon atom in C=C bond which carries maximum number of hydrogen atoms and the negative part of acid gets attached to that carbon atom in C=C bond which has minimum number of hydrogen atoms.

Answer 8

(b)

Interpretation Introduction

To determine: The conversion of 1−iodo−2−methylcyclopentane into 1−methylcyclopentanol.

Interpretation: The conversion of the given reactions is to be stated.

Concept introduction: The general steps followed by Oxymercuration-demercuration reaction are stated below:

Formation of mercurinium ion.

Attack of water on mercurinium ion to give alcohol.

Demercuration

Answer 9

(b)

Interpretation Introduction

To determine: The conversion of 1−iodo−2−methylcyclopentane into 1−methylcyclopentanol.

Interpretation: The conversion of the given reactions is to be stated.

Concept introduction: The general steps followed by Oxymercuration-demercuration reaction are stated below:

Formation of mercurinium ion.

Attack of water on mercurinium ion to give alcohol.

Demercuration

Answer 10

(c)

Interpretation Introduction

To determine: The conversion of 3−methylpent−1−ene into 3−methylpentan−2−ol.

Interpretation: The conversion of the given reactions is to be stated.

Concept introduction: Oxymercuration-demercuration is one of the methods used to convert alkenes into alcohols. This type of reaction follows Markovinokov’s rule.

According to Markovnikov’s rule, the positive part of acid gets attached to that carbon atom in C=C bond which carries maximum number of hydrogen atoms and the negative part of acid will attach to that carbon atom in C=C bond which has minimum number of hydrogen atoms.

The general steps followed by Oxymercuration-demercuration reaction are stated below:

Formation of mercurinium ion.

Attack of water on mercurinium ion to give alcohol.

Demercuration

Answer 11

(c)

Interpretation Introduction

To determine: The conversion of 3−methylpent−1−ene into 3−methylpentan−2−ol.

Interpretation: The conversion of the given reactions is to be stated.

Concept introduction: Oxymercuration-demercuration is one of the methods used to convert alkenes into alcohols. This type of reaction follows Markovinokov’s rule.

According to Markovnikov’s rule, the positive part of acid gets attached to that carbon atom in C=C bond which carries maximum number of hydrogen atoms and the negative part of acid will attach to that carbon atom in C=C bond which has minimum number of hydrogen atoms.

The general steps followed by Oxymercuration-demercuration reaction are stated below:

Formation of mercurinium ion.

Attack of water on mercurinium ion to give alcohol.

Demercuration

Answer 12

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Answer 13

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Answer 14

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Answer 15

Ch. 8.3A - Predict the major products of the following...Ch. 8.3A - a. When 1 mole of buta-1,3-diene reacts with 1...Ch. 8.3B - Predict the major products of the following...Ch. 8.3B - Show how you would accomplish the following...Ch. 8.4B - Propose a mechanism to show how...Ch. 8.4B - Predict the products of the following hydration...Ch. 8.6 - a. Propose a mochansm fortho following reaction....Ch. 8.6 - Prob. 8.8P Ch. 8.6 - Prob. 8.9P Ch. 8.7A - Prob. 8.10P

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