Concept explainers
(a)
To determine: The conversion of
Interpretation: The conversion of the given reactions is to be stated.
Concept introduction: Hydroboration reaction is a two step reaction, which involves conversion of
Anti Markovnikov’s rule states that the positive part of acid gets attached to that carbon atom in
(b)
To determine: The conversion of
Interpretation: The conversion of the given reactions is to be stated.
Concept introduction: Oxymercuration-demercuration is one of the methods used to convert alkenes into alcohols. This type of reaction follows Markovnikov’s rule.
According to Markovnikov’s rule, the positive part of acid gets attached to that carbon atom in
The general steps followed by Oxymercuration-demercuration reaction are stated below:
- Formation of mercurinium ion.
- Attack of water on mercurinium ion to give alcohol.
- Demercuration
(c)
To determine: The conversion of
Interpretation: The conversion of the given reactions is to be stated.
Concept introduction: Hydroboration reaction is a two step reaction, which involves conversion of alkene into alcohol. This type of reaction follows anti- Markovnikov’s rule.
Anti Markovnikov’s rule states that the positive part of acid gets attached to that carbon atom in
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Chapter 8 Solutions
Organic Chemistry (9th Edition)
- Name each alkyne. a. CH=C-CH-CH3 CH3 b. CH3-C=C-CH-CH-CH,-CH, CH3 CH3 c. CHEC-C-CH,-CH3 CH2 ČH, CH3 d. CH;-C=C-CH-C-CH, CH2 CH3 ČH3arrow_forwardIndicate the product obtained by reacting A and B. A || H3C-S-CH₂ Na* || CH 3 B CH2. C. CH3 H3C CH3arrow_forwardName each alkene. a. CH;=CH-CH;-CH3 CH, CH3 b. CH3-CH-c=CH-CH3 c. CH,=HC-CH–CH,-CH,-CH, CH3-CH ČH3 CH3 d. CH3-CH-CH=C-CH3 CH,-CH3arrow_forward
- 7. Reaction product of 3-methyl-butene with hydrochloric acid:a) 2-methyl-3-chlorobutaneb) 3-methyl-3-chlorobutanec) 2-chloro-3-methyl butaned) 2-chloro-2-methyl butane 8. What type of reaction takes place when CO2 + H2O and energy are obtained from 3-methyl butyne?a) Hydrogenationb) Halogenationc) Partial oxidationd) Total oxidationarrow_forwarda. The following compounds have the same molecular formula as benzene. How many monobrominated products could each form? 1. HC‚CC‚CCH2CH3 2. CH2“CHC‚CCH“CH2 b. How many dibrominated products could each of the preceding compounds form? (Do not include stereoisomers.) c. How many dibrominated products could each of the compounds form if stereoisomers are included?arrow_forwardWhat about the second step in the electrophilic addition of HCl to an alkene-the reaction of chloride ion with the carbocation intermediate? Is this step exergonic or endergonic? Does the transition state for this second step resemble the reactant (carbocation) or the product (alkyl chloride)? Make a rough diagram of what the transition state may look like?arrow_forward
- Determine the products of each carboxylic acid reaction. a. CH3-CH2-CH2-CH,-C-OH + H,SO, CH, — CH,— он HO. b. CH2 heat CH2 C-OH CH2arrow_forwardThe major organic product of the following reaction is HC=CH2 H2/ Ni-Cat. HC=C-CH2 HC=CH2 H2 1. H3C-C -CH2 H2C-CH3 H2 H3C-C-CH2 HC=CH2 H3C-C-CH2 HC=CH2 H2C=C-CH2 H. H2C-CH3 HC=C-CH2arrow_forwardIn a phrase or short sentence, explain why this reaction is not successful. NACN H2C=CHCH3 H2C=CHCH2CN A------------- ->arrow_forward
- 2. Draw the product/s especially the structure of the alkane produced in each of the following reactions Reaction Product/s a. C,H16 + O2 b. Butane+ CI, c. Propanearrow_forwardDraw the product(s) of the following reactions. CH3 H₂C-C-CEC-H OH 1. BH3/THF 2. H₂O₂/ aqueous NaOH • You do not have to consider stereochemistry. Separate multiple products using the + sign from the drop-down menu. • You do not have to explicitly draw H atoms. • If no reaction occurs, draw the organic starting material.arrow_forwardWhat is the product of 3,3,5-trimethylheptan-4-ol with HBr? i. 4-bromo-3,3,5-trimethylheptane ii. 3-bromo-3,4,5-trimethylheptane iii.5-bromo-3,3,4-trimethylheptane iv. 4-bromo-3,3,5-trimethylheptanearrow_forward
Organic ChemistryChemistryISBN:9781305580350Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. FootePublisher:Cengage Learning