Organic Chemistry
Organic Chemistry
6th Edition
ISBN: 9781936221349
Author: Marc Loudon, Jim Parise
Publisher: W. H. Freeman
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Chapter 19, Problem 19.19P
Interpretation Introduction

(a)

Interpretation:

An aldehyde or ketone that is required to synthesize the given alcohol compound by the reduction with either LiAlH4 or NaBH4 is to be stated.

Concept introduction:

The reduction of an aldehyde or ketone in the presence of a hydride like LiAlH4 and NaBH4 forms the corresponding alcohol. The reduction of an aldehyde forms a primary alcohol and the reduction of a ketone forms a secondary alcohol.

Interpretation Introduction

(b)

Interpretation:

An aldehyde or ketone that is required to synthesize the given alcohol compound by the reduction with either LiAlH4 or NaBH4 is to be stated.

Concept introduction:

The reduction of an aldehyde or ketone in the presence of a hydride like LiAlH4 and NaBH4 forms the corresponding alcohol. The reduction of an aldehyde forms a primary alcohol and the reduction of a ketone forms a secondary alcohol.

Interpretation Introduction

(c)

Interpretation:

An aldehyde or ketone that is required to synthesize the given alcohol compound by the reduction with either LiAlH4 or NaBH4 is to be stated.

Concept introduction:

The reduction of an aldehyde or ketone in the presence of a hydride like LiAlH4 and NaBH4 forms the corresponding alcohol. The reduction of an aldehyde forms a primary alcohol and the reduction of a ketone forms a secondary alcohol.

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Students have asked these similar questions
(a) How will you convert:(i) Benzene to acetophenone                 (ii) Propanone to 2-Methylpropan-2-ol(b) Give reasons :(i) Electrophilic substitution in benzoic acid takes place at meta position.(ii) Carboxylic acids are higher boiling liquids than aldehydes, ketones and alcohols of comparable molecular masses.(iii) Propanal is more reactive than propanone in nucleophilic addition reactions.
(b) State the reagents needed to convert benzoic acid into the following compounds. (i) C6H§COCI (ii) C,H$CH2OH (iii) C6H$CONHCH3
Draw line structures of the following compounds and the product you would obtain from the reduction of each.(a) Isopropyl methyl ketone (b) p-Hydroxybenzaldehyde(c) 2-Methylcyclopentanone

Chapter 19 Solutions

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