Organic Chemistry
Organic Chemistry
6th Edition
ISBN: 9781936221349
Author: Marc Loudon, Jim Parise
Publisher: W. H. Freeman
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Chapter 19, Problem 19.54AP
Interpretation Introduction

Interpretation:

The compound A formed as the intermediate in the reaction between ethynylbenzene and methanol is to identified. The mechanism for the reaction between ethynylbenzene and methanol is to be drawn.

Concept introduction:

The addition reaction the protic acid is added to an asymmetric alkene and the atatchement of acidic hydrogen takes place to highly substituted carbon is known as Markonikov’s reaction. The Markonikov’s rule states that a hydrogen atom is always added to the highly substituted carbon atom.

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(a) Draw the mechanism for the formation of both of the enols that can be formed from A (use acetic acid & AcOH as the source of the protons) (b) Draw the mechanism of reaction of this enol with bromine to give product B
(a) Explain why an alkylamine is more basic than ammonia?(b) How would you convert(i) Aniline to nitrobenzene (ii) Aniline to iodobenzene
Give the structure of compound A.

Chapter 19 Solutions

Organic Chemistry

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