(a)
Interpretation:
A mechanism for the reaction of two equivalents of the methyllithium with carboxylic acids to produce
Concept introduction:
Organolithium reagents are very reactive
(b)
Interpretation:
The product of the given reaction is to be stated.
Concept introduction:
Organolithium reagents are very reactive organometallic compounds. These compounds attack directly on the carbonyl carbon of carbonyl compounds. The organolithium compounds are very strong base and therefore, undergo acid-base reactions very quickly.
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Organic Chemistry
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- Give reasons: (i) Bond length of C = O in carboxylic acids is slightly larger than C = O bond length in carbonyl compounds. (ii) There are two –NH2 groups in semicarbazide. However, only one –NH2 group is involved in the formation of semicarbazones. (iii) Benzoic acid is less soluble in water than acetic acid. (iv) Formic acid is a stronger acid than acetic acid.arrow_forward(a) How will you carry out the following conversions?(i) Acetylene to Acetic acid (ii) Toluene to m-nitrobenzoic acid(iii) Ethanol to Acetone(b) Give reasons :(i) Chloroacetic acid is stronger than acetic acid.(ii) pH of reaction should be carefully controlled while preparing ammonia derivatives of carbonyl compounds.arrow_forwardSynthesize from benzene. (Hint: All of these require diazonium ions.)(a) 3-ethylbenzoic acidarrow_forward
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- (b) Compound AA has a molecular formula of CsH&O and gives a positive result using Tollen's reagent. The reaction of compound AA with hot acidified potassium permanganate, KMNO4 gives compound BB. The catalytic hydrogenation of compound AA with nickel, Ni produced compound Cc. The reaction of compound BB with ethanamine, CH:CH2NH2 produces compound DD. Sebatian AA mempunyai formula molekul C3He0 dan memberikan keputusan yang positif menggunakan reagen Tollen. Tindak balas sebatian AA dengan larutan panas kalium permanganat, KMNO4 berasid menghasilkan sebatian BB. Penghidrogenan bermangkin bagi sebatian AA dengan nikel, Ni menghasilkan sebatian CC. Tindak balas sebatian BB dengan etanamina, CH3;CH2NH2 menghasilkan sebatian DD. (1) Draw the structural formula of compounds AA, BB, CC and DD. Lukiskan formula struktur bagi sebatian AA, BB, CC dan DD. (i) Name the type of chemical reaction for the formation of compound CC. Namakan jenis tindak balas kimia bagi penghasilan sebatian Cc.arrow_forwardWrite the equilibrium-constant expressions and obtainnumerical values for each constant in. (a) the basic dissociation of aniline, C6H5NH2. (b) the acidic dissociation of hypochlorous acid,HClO. (c) the acidic dissociation of methyl ammoniumhydrochloride, CH3NH3Cl. (d) the basic dissociation of NaNO2. (e) the dissociation of H3AsO3to H3O+and AsO33-. (f) the reaction of C2O42-with H2O to give H2C2O4and OH-. show solutionarrow_forwardAnswer ALL parts of this question. (a) Using resonance structures, discuss the following statement; phenols are much stronger acids than aliphatic alcohols. (b) Give the structure of a stronger organic acid than phenol. (c) Rationalise the acidity of the latter organic acid by drawing two resonance structures of the conjugate base. (d) Eugenol is a natural product derived from the dried flower buds of the evergreen tree, Eugenia aromatica. Briefly describe a procedure with reagents required to extract eugenol as a single component from the mixture of compounds present in these flower buds. OH LOCH 3 eugenolarrow_forward
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