Organic Chemistry
9th Edition
ISBN: 9781305080485
Author: John E. McMurry
Publisher: Cengage Learning
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Chapter 7.2, Problem 3P
Diazepam, marketed as an antianxiety medication under the name Valium, has three rings, eight double bonds, and the formula C16H?ClN2O. How many hydrogens does diazepam have? (Calculate the answer; don’t count hydrogens in the structure.)
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Write the systematic name of each organic molecule:
structure
O
||
H-C—CH-CH3
OH
H—C–CH2–CH2–CH3
||
HỌ—CH,—CH,—CH–CH
OH
name
Ú
0
0
Identify the functional group/s of the following organic compounds
`N
ОН
Соcaine
A°-Tetrahydrocannabinol (THC)
Lysergide (lysergic acid diethyl
amide, or LSD)
`NH
НО.
HN
+
H3N
ОН
Aspartame
(NutraSweet)
Theobromine
Caffeine
Azidothymidine (AZT)
ОН
F3C.
'N
H2
Penicillin G
НО
Propofol
Fluoxetine hydrochloride (Prozac)
HO
Na+
Dextromethamphetamine
Naproxen sodium (Aleve)
Acetylsalicylic acid (Aspirin)
Tamiflu®, the most effective antiviral drug used to treat avian influenza, has the following structure. Identify the indicated functional
groups in Tamiflu®.
II
ÑH2
O 1= ketone; I| = amine; III = alkene
O 1 = ester; I| = amide; III = alkyne
O 1 = amine; || = amide; III = alkene
O 1 = amide; || = amine; III = alkene
O 1 = amine; I| = amine; III = aromatic
Chapter 7 Solutions
Organic Chemistry
Ch. 7.2 - Calculate the degree of unsaturation in each of...Ch. 7.2 - Prob. 2PCh. 7.2 - Diazepam, marketed as an antianxiety medication...Ch. 7.3 - Give IUPAC names for the following compounds:Ch. 7.3 - Prob. 5PCh. 7.3 - Prob. 6PCh. 7.3 - Prob. 7PCh. 7.4 - Prob. 8PCh. 7.4 - Prob. 9PCh. 7.4 - Prob. 10P
Ch. 7.5 - Which member in each of the following sets ranks...Ch. 7.5 - Prob. 12PCh. 7.5 - Prob. 13PCh. 7.5 - Prob. 14PCh. 7.6 - Prob. 15PCh. 7.8 - Prob. 16PCh. 7.8 - Prob. 17PCh. 7.9 - Show the structures of the carbocation...Ch. 7.9 - Draw a skeletal structure of the following...Ch. 7.10 - Prob. 20PCh. 7.11 - On treatment with HBr, vinylcyclohexane undergoes...Ch. 7.SE - Prob. 22VCCh. 7.SE - Prob. 23VCCh. 7.SE - The following carbocation is an intermediate in...Ch. 7.SE - Prob. 25VCCh. 7.SE - Predict the major product and show the complete...Ch. 7.SE - Prob. 27MPCh. 7.SE - When 1, 3-butadiene reacts with one mole of HBr,...Ch. 7.SE - When methyl vinyl ether reacts with a strong acid,...Ch. 7.SE - Addition of HCl to 1-isopropylcyclohexene yields a...Ch. 7.SE - Addition of HCl to...Ch. 7.SE - Limonene, a fragrant hydrocarbon found in lemons...Ch. 7.SE - Prob. 33MPCh. 7.SE - Calculate the degree of unsaturation in the...Ch. 7.SE - Prob. 35APCh. 7.SE - Prob. 36APCh. 7.SE - Name the following alkenes:Ch. 7.SE - Draw structures corresponding to the following...Ch. 7.SE - Prob. 39APCh. 7.SE - Prob. 40APCh. 7.SE - Prob. 41APCh. 7.SE - Prob. 42APCh. 7.SE - Prob. 43APCh. 7.SE - Draw and name the 17 alkene isomers, C6H12,...Ch. 7.SE - Prob. 45APCh. 7.SE - Prob. 46APCh. 7.SE - Which of the following E, Z designations are...Ch. 7.SE - Prob. 48APCh. 7.SE - trans-2-Butene is more stable than cis-2-butene by...Ch. 7.SE - Prob. 50APCh. 7.SE - Normally, a trans alkene is more stable than its...Ch. 7.SE - trans-Cyclooctene is less stable than...Ch. 7.SE - Prob. 53APCh. 7.SE - Prob. 54APCh. 7.SE - Use Hammond’s Postulate to determine which...Ch. 7.SE - Prob. 56APCh. 7.SE - Predict the major product in each of the following...Ch. 7.SE - Prob. 58APCh. 7.SE - Prob. 59APCh. 7.SE - Prob. 60APCh. 7.SE - Allene (1,2-propadiene), H2C=C=CH2, has two...Ch. 7.SE - The heat of hydrogenation for allene (Problem...Ch. 7.SE - Retin A, or retinoic acid, is a medication...Ch. 7.SE - Prob. 64APCh. 7.SE - tert-Butyl esters [RC02C(CH3)3] are converted into...Ch. 7.SE - Vinylcyclopropane reacts with HBr to yield a...Ch. 7.SE - Prob. 67APCh. 7.SE - Prob. 68APCh. 7.SE - Prob. 69APCh. 7.SE - Prob. 70APCh. 7.SE - Prob. 71APCh. 7.SE - Reaction of 2, 3-dimethyl-l-butene with HBr leads...
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- Your chemistry professor draws a number of molecules on the board: (1) CH4 ; (2) H2C=CH2 ; (3) H2C=C=CH2 ; and (4) H2C=C=C=CH2. You muse about all the molecules that chemists draw on a two-dimensional board and wonder which ones are actually planar, existing basically as they appear on the board, and which ones are not plane but rather three-dimensional. Answer ALL of the following questions. What are the specific orbital overlaps (i.e., sp3-sp3) that are in each of the molecules? What are the bond angles for each central atom in each molecule? Which molecules are planar and which are non-planar?arrow_forwardYour chemistry professor draws a number of molecules on the board: (1) CH4 ; (2) H2C=CH2 ; (3) H2C=C=CH2 ; and (4) H2C=C=C=CH2. You muse about all the molecules that chemists draw on a two-dimensional board and wonder which ones are actually planar, existing basically as they appear on the board, and which ones are not plane but rather three-dimensional. Answer the following questions. What is the geometry and hybridization of the carbon in CH4? What is the geometry and hybridization of each central carbon atom in the remaining molecules? Draw each molecule showing the bonds and identify each bond in all the molecules as s or p. What are the specific orbital overlaps (i.e., sp3-sp3) that are in each of the molecules? What are the bond angles for each central atom in each molecule? Which molecules are planar and which are non-planar?arrow_forward(b) P alcohol OH AVI // 1. H3PO4 2. Os04 3. NaHSO3 Q در ? Ⓡ ChemDoodlearrow_forward
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- what does a benzene C6H6 look like in a model? Is it linear, trigonal planar or tetrahedral? What are the bond angles? Is it flexible or rigid?arrow_forwardDraw three (3) Lewis Structures that fit the following formula: C5H1NO You must have one each of the following classes of compounds in your answer: i) ketone and amine ii) amide iii) epoxide and aminearrow_forwardAromatic compounds got their name because many have strong smells. Benzene, toluene, aniline, and phenol are common structures from which most aromatic compounds are derived. (Figure 1) When naming aromatic compounds with three or more substituents, the ring is numbered to give the smallest possible set of numbers. For example, this phenol derivative (Figure 2) is called 4-bromo-3-chlorophenol. The substituents Figure CH3 NH₂ 1 of 2 > OH benzene toluene aniline phenol Name the following molecule by its IUPAC name. ► View Available Hint(s) Submit Part B Name the following molecule by its IUPAC name. CI Br CH3 CI Brarrow_forward
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